Publication list
[139] Nisters, A., Schleuning, S., Buntkowsky, G., Gutmann, T., Rose, M.* Hyper-crosslinked polyphosphines as nanoporous macroligands – a systematic study on crosslinking and their catalytic application in the CO2 hydrogenation. ACS Appl. Mater. Interfaces 17, (2025), 1244–1258. DOI: 10.1021/acsami.4c17605 [138] Hoffmann, M.*, Gutmann, T., Buntkowsky, G.* Thermal Behavior of n-Octanol and Related Ether Alcohols. J. Chem. Eng. Data 70, (2025), 600−606. DOI: 10.1021/acs.jced.4c00525 [137] Wissel, T., Rösler, L., Brodrecht, M., Höfler, M. V., Herr, K., de Oliveira jr., M., Klimavicius, V., Ebert, M., Breitzke, H., Hoffmann, H., Buntkowsky, G.*, Gutmann, T.* Novel Heterogeneous Pd Catalysts for Cross-Coupling Reactions in Biocompatible Media – Structural Insights from Solid-State NMR Techniques. Chem. Cat. Chem., (2024), e202401511. DOI: 10.1002/cctc.202401511 [136] Höfler, M. V., Lins, J., Seelinger, D., Pachernegg, L., Schäfer, T., Spirk, S., Biesalski, M., Gutmann, T.* DNP enhanced solid-state NMR – A powerful tool to address the surface functionalization of cellulose/paper derived materials. J. Magn. Reson. Open 21, (2024), 100163. DOI: 10.1016/j.jmro.2024.100163 [135] Nisters, A., Gutmann, T., Kim, S. M., Hofmann, J. P., Rose, M.* A solid xantphos macroligand based on porous organic polymers for the catalytic hydrogenation of CO2. RSC Sustainability 2, (2024), 2213–2217. DOI: 10.1039/D4SU00164H [134] Haro Mares, N., Logrado, M., Kergassner, J., Zhang, B., Gutmann, T.*, Buntkowsky, G.* Solid-state NMR of heterogeneous Catalysts. Chem. Cat. Chem., (2024), e202401159 DOI: 10.1002/cctc.202401159 [133] Wunder, C., Lai, T.-L., Šić, E., Gutmann, T., de Vito, E., Buntkowsky, G., Zarrabeitia, M.*, Passerini, S.* Sodium 4-styrenesulfonyl(trifluoromethanesulfonyl)imide-based Single-Ion Conducting Polymer Electrolyte Incorporating Molecular Transporters for Solid-State Sodium Batteries. J. Mater. Chem. A 12, (2024), 20935–20946. DOI: 10.1039/D4TA02329C [132] Hoffmann, M. H.*, Gonzalez, A. A., Huynh, M. T., Miller, K. K., Gutmann, T., Buntkowsky, G.* Densities, Viscosities, and Self-Diffusion Coefficients of Octan-1-ol and Related Ether-Alcohols. J. Chem. Eng. Data 69, (2024), 2688-2699. DOI: 10.1021/acs.jced.4c00195 [131] Herr, K., Höfler, M. V., Heise, H., Aussenac, F., Kornemann, F., Rosenberger, D., Brodrecht, M., de Oliveira Jr. M., Buntkowsky, G.*, Gutmann, T.* Biradicals based on PROXYL Containing Building Blocks for Efficient Dynamic Nuclear Polarization in Biotolerant Media. JMRO 20, (2024), 100152. DOI: 10.1016/j.jmro.2024.100152 [130] Hutsch, S., Leonard, A., Grätz, S., Höfler, M.-V., Gutmann, T., Borchardt, L.* Mechanochemical Cyclotrimerization: A Versatile Tool to Covalent Organic Frameworks with Tunable Stacking Mode. Angew. Chem. Int. Ed. 63, (2024), e202403649. DOI: 10.1002/anie.202403649 [129] Kunkel, B., Seeburg, D., Kabelitz, A., Witte, S., Gutmann, T., Breitzke, H., Buntkowsky, G., Buzanich, A. G.*, Wohlrab, S.* Highly productive V/Zn-SiO2 catalysts for the selective oxidation of methane. Catal. Today 432, (2024), 114643. DOI: 10.1016/j.cattod.2024.114643 [128] Šić, E., Fredericks, D., Pecher, O., Wegner, S., Breitzke, H., Singh, V., Buntkowsky, G.* Gutmann, T.* Towards Routine 7Li In-Situ Solid-State NMR Studies of Electrochemical Processes in Li|LiPF6|LFP Cells. Appl. Magn. Reson. 55 (2024), 575–583. DOI: 10.1007/s00723-024-01643-1 [127] Hillscher, L. M., Höfler, M. V., Gutmann, T.*, Lux, C., Clerkin, K. U., Schwall, G., Villforth, K., Schabel, S., Biesalski, M.* Influence of TEMPO-Oxidation on Pulp Fiber Chemistry, Morphology and Mechanical Paper Sheet Properties. Cellulose 31 (2024), 3067–3082. DOI:10.1007/s10570-024-05748-5 [126] Nasemann, S., Franz, R., Kargin, D., Bruhn, C., Kelemen, Z., Gutmann, T., Pietschnig, R.* At the Limits of Bisphosphonio-substituted Stannylenes. Chem. Asian J. 19, (2024), e202300950. DOI: 10.1002/asia.202300950 [125] Limprasart, W., Höfler, M. V., Kunzmann, N., Rösler, L., Herr, K., Breitzke, H., Gutmann, T.* Peptides as Model Systems for Biofunctionalizations of Cellulose – Synthesis and Structural Characterization by Advanced Solid-State NMR Techniques. J. Phys. Chem. C 127, (2023), 22129–22138. DOI:10.1021/acs.jpcc.3c05068 [124] Šić, E., Schutjajew, K., Haagen, U., Breitzke, H., Oschatz, M., Buntkowsky, G.*, Gutmann, T.* Electrochemical Sodium Storage in Hard Carbon Powder Electrodes Implemented in an Improved Cell Assembly: Insights from In-Situ and Ex-Situ Solid-State NMR. ChemSusChem, (2023), e202301300. DOI: 10.1002/cssc.202301300 [123] Haro Mares, N., Brodrecht, M., Wissel, T., Döller, S. C., Rösler, L., Breitzke, H., Hoffmann, M., Gutmann, T.*, Buntkowsky, G.* Influence of APTES-Decorated Mesoporous Silica on the Dynamics of Ethylene Glycol Molecules – Insights from Variable Temperature 2H Solid-State NMR. J. Phys. Chem. C 127, (2023), DOI: 10.1021/acs.jpcc.3c03671 [122] Döller, S. C., Brodrecht, M., Gutmann, T., Hoffmann, M., Buntkowsky, G.* Direct and Indirect DNP NMR Uncovers the Interplay of Surfactants with their Mesoporous Host Material. J. Phys. Chem. C 127, (2023), 12125–12134. DOI: 10.1021/acs.jpcc.3c01946 [121] Schumacher, L., Pfeiffer, J., Shen, J., Gutmann, T., Breitzke, H., Buntkowsky, G., Hofmann, K., Hess, C.* Collaborative Mechanistic Effects between Vanadia and Titania during the Oxidative Dehydrogenation of Propane Investigated by Operando and Transient Spectroscopy. ACS Catalysis 13, (2023), 8139–8160. DOI: 10.1021/acscatal.3c01404 [120] Šić, E., Rohrer, J.*, Ricohermoso, E., Albe, K., Ionescu, E., Riedel, R., Breitzke, H., Gutmann, T.*, Buntkowsky, G.* SiCO Ceramics as Storage Materials for Alkali Metals/Ions – Insights on Structure Moieties from Solid-State NMR and DFT Calculations. ChemSusChem, (2023), e202202241. DOI: 10.1002/cssc.202202241 [119] Asanbaeva, N. B., Dobrynin, S. A., Morozov, D. A., Haro-Mares, H., Gutmann, T., Buntkowsky, G., Bagryanskaya, E. G.* An EPR Study on Highly Stable Nitroxyl-nitroxyl Biradicals for Dynamic Nuclear Polarization Applications at High Magnetic Fields. Molecules 28, (2023), 1926. DOI: 10.3390/molecules28041926 [118] Hoffmann, M. M.*, Randall, N. P., Apak, M. H., Paddock, N. A., Gutmann, T., Buntkowsky, G.* Solute-Solvent Interactions of 2,2,6,6-Tetramethylpiperidinyloxyl and 5-Tert-butylisophthalic Acid in Polyethylene Glycol as Observed by Measurements of Density, Viscosity, and Self-Diffusion Coefficient. J. Solut. Chem. 52, (2023), 685–707. DOI: 10.1007/s10953-023-01265-4 [117] Höfler, M. V., Limprasart, W., Rösler, L., Fleckenstein, M., Brodrecht, M., Herr, K., Schäfer, J.-L., Biesalski, M., Breitzke, H., Gutmann, T.*, Fluorine Labeled N-Boc-L-Proline as Marker for Solid-State NMR Characterization of Biofunctionalizations on Paper Substrates. J. Phys. Chem C 117, (2023), 3570–3578. DOI: 10.1021/acs.jpcc.2c08370 [116] ] Krusenbaum, A., Kraus, F. J. L., Hutsch, S., Grätz, S., Höfler, M. V., Gutmann, T., Borchardt, L.*, The Rapid Mechanochemical Synthesis of Microporous Covalent Triazine Networks: Elucidating the Role of Chlorinated Linkers by a Solvent‑free Approach. Adv. Sustain. Syst., (2023), 2200477. DOI: 10.1002/adsu.202200477 [115] ] König, J., Gutmann, T., Buntkowsky, G., Köckerling, M.*, Strong Cluster Supported Brønsted Acids: Hexanuclear Niobium Cluster Compounds with Protonated Crown Ether Cations: (Crown-H)2[Nb6Cli12Xa6] (X = Cl or Br) and the Intermediate [Nb6Cl16(H2O)2]⋅4(dioxane). Inorg. Chem. 61, (2022), 15983-15990. DOI: 10.1021/acs.inorgchem.2c02279 [114] Buntkowsky, G.*, Gutmann, T., PASADENA NMR, Nat. Catal. 5 (2022), 848-849. DOI: 10.1038/s41929-022-00890-4 [113] Döller, S. C., Gutmann, T., Hoffmann, M., Buntkowsky, G.*, A Case Study on the Influence of Hydrophilicity on the Signal Enhancement by Dynamic Nuclear Polarization. Solid-state NMR 122, (2022), 101829. DOI: 10.1016/j.ssnmr.2022.101829 [112] Asanbaeva, N. B., Gurskaya, L. Y., Polienko, Y. F., Rybalova, T., V., Kazantsev, M. S., Dmitriev, A. A., Gritsan, N. P., Haro-Mares, N., Gutmann, T., Buntkowsky, G., Tretyakov, E. V., Bagryanskaya, E. G.*, Effects of Spiro-Cyclohexane Substitution of Nitroxyl Biradicals on Dynamic Nuclear Polarization. Molecules 27, (2022), 3252. DOI: 10.3390/molecules27103252 [111] Rösler, L., Höfler, M. V., Breitzke, H., Wissel, T., Herr, K., Heise, H., Gutmann, T.*, Buntkowsky, G.*, Dirhodium complex immobilization on modified cellulose for highly selective heterogeneous cyclopropanation reactions. Cellulose 29, (2022), 6283-6299. DOI: 10.1007/s10570-022-04654-y [110] Sic, E., Melzi d'Eril, M., Schutjajew, K., Graczyk-Zajac, M., Breitzke, H., Riedel, R., Oschatz, M., Gutmann, T*, Buntkowsky, G.*, SiCN Ceramics as Electrode Materials for Sodium/Sodium Ion Cells – Insights from 23Na In-situ Solid-State NMR. Batter. Supercaps 5, (2022), e202200066. DOI: 10.1002/batt.202200066 [109] Dey, S., Kargin, D., Höfler, M. V., Szathmári, B., Bruhn, C., Gutmann, T., Kelemen, Z.*, Pietschnig, R.*, Oligo- and Polymerization of Phospha[2]Ferrocenophanes to one dimensional phosphorus chains with ferrocenylene handles. Polymer 242, (2022), 124589. DOI: 10.1016/j.polymer.2022.124589 [108] Hoffmann, M. M.*, Kealy, J. D., Gutmann, T., Buntkowsky, G.* Densities, Viscosities, and Self-Diffusion Coefficients of Several Polyethylene Glycols. J. Chem. Eng. Data 67, (2022), 88-103. DOI: 10.1021/acs.jced.1c00759 [107] Dey, S., Roesler, F., Höfler, M. V., Bruhn, C., Gutmann, T.*, Pietschnig, R.* Synthesis, Structure and Cu-Acetylide Coordination of an Unsymmetrically Substituted Bulky dppf-Analog. Eur. J. Inorg. Chem. 2022, (2022), e202100939. DOI: 10.1002/ejic.202100939 [106] Krusenbaum, A., Geisler, J., Kraus, F. J. L., Grätz, S., Höfler, M. V., Gutmann, T., Borchardt, L.* The Mechanochemical Friedel Crafts Polymerization as a Solvent-free Cross-linking Approach towards Microporous Polymers. J. Polym. Sci. 60, (2022), 62-71. DOI: 10.1002/pol.20210606 [105] Buntkowsky, G.*, Döller, S., Haro-Mares, N., Gutmann, T., Hoffmann, M., Solid-state NMR studies of non-ionic surfactants confined in mesoporous silica. Z. Phys. Chem. 236, (2022), 939-960. DOI: 10.1515/zpch-2021-3132 [104] Döller, S. C., Brodrecht, M., Haro Mares, N., Breitzke, H., Gutmann, T., Hoffmann, M., Buntkowsky, G.* Deuterium NMR Studies of the Solid-Liquid Phase Transition of Octanol-d17 Confined in SBA-15. J. Phys. Chem C 125, (2021), 25155–25164. DOI: 10.1021/acs.jpcc.1c05873 [103] Höfler, M. V., Hoinka, N., Schäfer, T., Horn, M., Aussenac, F., Fuhrmann-Lieker, T.*, Gutmann, T.*, Light Amplification Materials based on Biopolymers doped with Dye Molecules – Structural Insights from 15N and 13C Solid state Dynamic Nuclear Polarization. J. Phys. Chem C 125, (2021), 21550–21558. DOI: 10.1021/acs.jpcc.1c06737 [102] Klintuch, D., Höfler, M., Wissel, T., Bruhn, C., Gutmann, T.*, Pietschnig, R.* Trifunctional silyl groups as anchoring units in the preparation of luminescent phosphole-silica hybrids. Inorg. Chem. 60, (2021), 14263–14274. DOI: 10.1021/acs.inorgchem.1c01775 [101] Li, Z., Rösler, L., Wissel, T., Breitzke, H., Gutmann, T.*, Buntkowsky, G.* Immobilization of a Chiral Dirhodium Catalyst on SBA-15 via Click-Chemistry: Application in the Asymmetric Cyclopropanation of 3-Diazooxindole with Aryl Alkenes. J. CO2 Util. 52, (2021), 101682. DOI: 10.1016/j.jcou.2021.101682 [100] Venel, F., Nagashima, H., Rankin, A. G. M., Anquetil, C., Klimavicius, V., Gutmann, T., Buntkowsky, G., Derenne, S., Lafon, O.,* Huguet, A., Pourpoint, F.* Characterization of functional groups in estuarine dissolved organic matter by DNP-enhanced 15N and 13C solid-state NMR. Chem. Phys. Chem. 22, (2021), 1907-1913. DOI: 10.1002/cphc.202100334 [99] Herr, K., Fleckenstein, M., Brodrecht, M., Höfler, M., Gutmann, T., Reggelin, M.*, Buntkowsky, G.* A Novel Strategy for Site Selective Spin-Labeling to Investigate Bioactive Entities by DNP and EPR Spectroscopy. Sci. Rep.11, (2021), 13714. DOI: 10.1038/s41598-021-92975-6 [98] de Oliveira Jr, M., Herr, K., Brodrecht, M., Haro-Mares, N., Wissel, T., Klimavicius, V., Breitzke, H., Gutmann, T., Buntkowsky, G.* Solvent-free dynamic nuclear polarization enhancements in organically modified mesoporous silica. Phys. Chem. Chem. Phys. 23, (2021), 12559-12568. DOI: 10.1039/D1CP00985K [97] Rothermel, N., Limbach, H.-H., del Rosal, I., Poteau, R.*, Mencia, G., Chaudret, B., Buntkowsky, G.*, Gutmann, T.* Surface reactions of ammonia on ruthenium nanoparticles revealed by 15N and 13C solid-state NMR. Catal. Sci. Technol. 11, (2021), 4509 – 4520. DOI: 10.1039/D0CY02476G [96] Hoffmann, M. M.*, Horowitz, R. H., Gutmann, T., Buntkowsky, G.* Densities, Viscosities and Self-Diffusion Coefficients of Ethylene Glycol Oligomers. J. Chem. Eng. Data 66, (2021), 2480–2500. DOI: 10.1021/acs.jced.1c00101 [95] Pietruschka, D., Kumari, B., Buntkowsky, G., Gutmann, T.*, Mollenhauer, D.* On the mechanism of Heterogenization of Dirhodium Catalysts: Insights from DFT calculations. Inorg. Chem. 60, (2021), 6239–6248. DOI: 10.1021/acs.inorgchem.0c03712 [94] van der Zwan, K., Riedel, W., Aussenac, F., Reiter, C., Kreger, K., Schmidt, H.-W., Risse, T., Gutmann, T.*, Senker, J.* 19F MAS DNP for Probing Molecules in Nanomolar Concentrations: Direct Polarization as Key for NMR Spectra without Solvent and Matrix Signals. J. Phys. Chem. C 125, (2021), 7287−7296. DOI: 10.1021/acs.jpcc.1c01167 [93] Klimavicius, V., Hilbig, H., Gutmann, T.*, Buntkowsky, G.* Direct Observation of Carbonate Formation in Partly Hydrated Tricalcium Silicate by Dynamic Nuclear Polarization Enhanced NMR Spectroscopy. J. Phys. Chem. C 125, (2021), 7321−7328. DOI: 10.1021/acs.jpcc.0c10382 [92] Srour, M., Hadjiali, S., Brunnengräber, K., Weidler, H., Xu, Y., Breitzke, H., Gutmann, T.*, Buntkowsky, G.* A Novel Wilkinson’s Type Silica Supported Polymer Catalyst – Insights from solid-state NMR and hyperpolarization techniques. J. Phys. Chem. C 125, (2021), 125, 7178−7187. DOI: 10.1021/acs.jpcc.1c00112 [91] Li, Z., Rösler, L., Wissel, T., Breitzke, H., Hofmann, K., Limbach, H.-H., Gutmann, T.*, Gerd Buntkowsky*. Design and Characterization of Novel Dirhodium Coordination Polymers – The Impact of Ligand Size on Selectivity in Asymmetric Cyclopropanation. Catal. Sci. Technol., (2021), DOI: 10.1039/D1CY00109D [90] Monteiro, A. S., de Oliveira Jr., M., Santagneli, S., Carcel, C., Gutmann, T., Buntkowsky, G., Chi Man, M. W., Barud, H. S., Ribeiro. S. J. L.* Modification of Bacterial Cellulose Membrane with 1,4-bis(triethoxysilyl)benzene: A thorough physical-chemical characterization study. J. Phys. Chem. C 125, (2021), 4498–4508. [89] Liu, P., Liu, H., Schäfer, T., Gutmann, T., Gibhardt, H., Qi, H., Tian, L., Zhang, X. C., Buntkowsky, G., Zhang, K.*, Unexpected Selective Alkaline Periodate Oxidation of Chitin for the Isolation of Chitin Nanocrystals. Green Chemistry 23, (2021), 745-751. DOI: 10.1039/D0GC04054A [88] Ratajczyk, T.*, Buntkowsky, G., Gutmann, T., Fedorczyk, B., Mames, A., Pietrzak, M., Puzio, Z., Szkudlarek, P. G. Resonance Signal Amplification by Reversible Exchange of Selective PyFALGEA Oligopeptide Ligands Towards Epidermal Growth Factor Receptors. Chem. Bio. Chem., (2020), 855-860. DOI:10.1002/cbic.202000711 [87] Grätz, S., de Olivera Jr., M., Gutmann, T.*, Borchardt, L.*, A comprehensive approach for the Characterization of Porous Polymers by 13C and 15N Dynamic Nuclear Polarization NMR Spectroscopy. Phys. Chem. Chem. Phys., (2020), 23307-23314. DOI: 10.1039/D0CP04010J [86] Hoffmann, M.*, Too, M., Vogel, M., Gutmann, T., Buntkowsky, G. Breakdown of the Stokes-Einstein Equation for Solutions of Water in Oil Reverse Micelles. J. Phys. Chem. B, (2020), 124, 9115–9125. DOI: 10.1021/acs.jpcb.0c06124 [85] Li, Z., Rösler, L., Herr, K., Brodrecht, M., Breitzke, H., Hofmann, K., Limbach, H.-H., Gutmann, T.*, Buntkowsky, G.* Dirhodium Coordination Polymers for Asymmetric Cyclopropanation of Diazooxindoles with Olefins: Synthesis and Spectroscopic Analysis. ChemPlusChem 85, (2020), 1737-1746. DOI: 10.1002/cplu.202000421 [84] Schäfer, T., Buntkowsky, G.*, Gutmann, T.* Solid-State NMR as versatile tool to identify the main chemical components of epoxy-based thermosets. ACS Omega, (2020), 5412-5420. DOI: 10.1021/acsomega.9b04482 [83] Hoffmann, M.*, Bothe, S., Brodrecht, M., Klimavicius, V., Haro-Mares, N., Gutmann, T.* Buntkowsky, G.* Direct and Indirect Dynamic Nuclear Polarization Transfer Observed in Mesoporous Materials Impregnated with Nonionic Surfactant Solutions of Polar Polarizing Agents. J. Phys. Chem C, (2020), 5145-5156. DOI: 10.1021/acs.jpcc.9b1050 [82] Groszewicz, P. B., Mendes, P., Kumari, B., Lins, J., Biesalski, M., Gutmann, T.*, Buntkowsky, G.* N-Hydroxysuccinimide-activated esters as a functionalization agent for amino cellulose: synthesis and solid-state NMR characterization. Cellulose 27, (2020), 1239–1254. DOI: 10.1007/s10570-019-02864-5 [81] de Oliveira Jr, M., Seeburg, D., Weiss, J., Wohlrab, S., Buntkowsky, G.*, Bentrup, U.*, Gutmann, T.* Structural characterization of vanadium environments in MCM-41 molecular sieve catalysts by solid state 51V NMR. Catal. Sci. Technol. 9, (2019), 6180–6190. DOI: 10.1039/C9CY01410A [80] Kumari, B., Brodrecht, B., Gutmann, T., Breitzke, H.*, Buntkowsky,G.* Efficient Referencing of FSLG-CPMAS-HETCOR Spectra using 2D 1H MAS FSLG. App. Magn. Reson. 50, (2019), 1399-1407. DOI: 10.1007/s00723-019-01156-2 [79] Sato, K*, Hirao, R., Timofeev, I., Krumkacheva, O., Zaytseva, E., Rogozhnikova, O., Tormyshev, V. M., Trukhin, D., Bagryanskaya, E.*, Gutmann, T., Klimavicius, V., Buntkowsky, G., Kenji Sugisaki, Nakazawa, S., Matsuoka, H., Toyota, K., Shiomi, D., Takui, T.* Trityl-Aryl-Nitroxide-Based Genuinely g Engineered Biradicals, As Studied by Dynamic Nuclear Polarization, Multifrequency ESR/ENDOR, Arbitrary Wave Generator Pulse Microwave Waveform Spectroscopy, and Quantum Chemical Calculations. J. Phys. Chem A, (2019), 7507-7517. DOI: 10.1021/acs.jpca.9b07169 [78] Neumann, S., Gutmann, T., Buntkowsky, G., Paul, S., Thiele, G., Sievers, H., Bäumer, M., Kunz, S.* Insights into the Reaction Mechanism and Particle Size Effects of CO Oxidation over Supported Pt Nanoparticles Catalysts. J. Catal. 377, (2019), 662-672. DOI: 10.1016/j.jcat.2019.07.049 [77] Nguyen, K., Kutzscher, C., Ehrling, S., Senkovska, I., Bon. V., de Oliveira Jr., M., Gutmann, T., Buntkowsky, G., Kaskel, S.* Insights into the Role of Zirconium in Proline Functionalized Metal-Organic Frameworks attaining high Enantio- and Diastereoselectivity. J. Catal. 377, (2019), 41-50. DOI: 10.1016/j.jcat.2019.07.003 [76] Klimavicius, V., Neumann, S., Kunz, S., Gutmann, T.*, Buntkowsky, G.* Room temperature CO oxidation catalysed by supported Pt nanoparticles revealed by solid-state NMR and DNP spectroscopy. Catal. Sci. Technol. 9, (2019), 3743–3752. DOI: 10.1039/c9cy00684b [75] Brodrecht, M., Herr, K., Bothe, S., de Oliveira Jr., M., Gutmann, T., Buntkowsky, G.* Efficient building-blocks for solid state peptide synthesis of spin-labeled peptides for EPR and DNP applications. Chem. Phys. Chem. 20, (2019), 1475-1487. DOI: 10.1002/cphc.201900211 [74] Brodrecht, M., Kumari, B., Thankamony, A. S. L., Breitzke, H., Gutmann, T.*, Buntkowsky*, G., Structural insights into peptides bound to the surface of silica nanopores, Chem. Eur. J., (2019), 5214-5221. DOI: 10.1002/chem.201805480 [73] Hadjiali, S., Savka, R., Plaumann, M., Bommerich, U., Bothe, S., Gutmann, T., Ratajczyk, T., Bernarding, J., Limbach, H.-H., Plenio, H., Buntkowsky, G.*, Substituent influences on the NMR signal amplification of Ir complexes with heterocyclic carbene ligands, Appl. Magn. Reson., (2019), 895–902. DOI:10.1007/s00723-019-01115-x [72] Rothermel, N., Röther, T., Ayvalı, T., Martínez-Prieto, L. M., Philippot, K., Limbach, H.-H., Chaudret, B.*, Gutmann, T.*, Buntkowsky, G.*, Reactions of D2 with 1,4-Bis(diphenylphosphino)butane stabilized Metal Nanoparticles – A combined gas-phase NMR, GC-MS and solid-state NMR Study, Chem. Cat. Chem. 11, (2019), 1465-1471. DOI: 10.1002/cctc.201801981R1 [71] Gutmann, T.*, Groszewicz, P., Buntkowsky, G.*, Solid-state NMR of nanocrystals. Annual Reports on NMR Spectroscopy, (2019), 1-82. DOI: 10.1016/bs.arnmr.2018.12.001 [70] Schäfer, T., Vowinkel, S., Breitzke, H., Gallei, M., Gutmann, T.*, Selective DNP Signal Amplification to Probe Structures of Core-Shell Polymer Hybrid Nanoparticles. J. Phys. Chem. C 123, (2019), 644-652. DOI: 10.1021/acs.jpcc.8b07969 [69] Dagys, L., Klimavicius, V., Gutmann, T., Buntkowsky, G., Balevicius, V.*, Quasi-Equilibria and Polarization Transfer Between Adjacent and Remote Spins: 1H–13C CP MAS Kinetics in Glycine. J. Phys. Chem. A 45, (2018), 8938-8947. DOI: 10.1021/acs.jpca.8b0903 [68] Vowinkel, S., Boehm, A., Schäfer, T., Gutmann, T., Ionescu, E., Gallei, M.*, Preceramic Core-Shell Particles for the Preparation of Hybrid Colloidal Crystal Films by Melt-Shear Organization and Conversion into Porous Ceramics. Materials and Design 160, (2018), 926-935 DOI: 10.1016/j.matdes.2018.10.032 [67] Brodrecht, M., Breitzke, H., Gutmann, T., Buntkowsky, G.*, Bio-functionalization of nano channels by direct in-pore solid phase peptide synthesis. Chem. Eur. J. 24, (2018), 17814-17822 DOI: 10.1002/chem.201804065 [66] Liu, J., Xu, Y., Groszewicz, P., Brodrecht, M., Fasel,C., Hofmann, K., Tan, X., Gutmann, T.*, Buntkowsky, G.*, Novel Dirhodium Coordination Polymers: The Impact of Side Chains on Cyclopropanation, Catal. Sci. Technol. 8, (2018), 5190-5200. DOI: 10.1039/C8CY01493K [65] Liu, P., Pang, B., Tian, L., Schäfer, T., Gutmann, T., Liu, H., Volkert, C. A., Buntkowsky, G., Zhang, K.*, Efficient, self-terminating isolation of cellulose nanocrystals via periodate oxidation in Pickering emulsions, ChemSusChem 11, (2018), 3581-3585. DOI: 10.1002/cssc.201801678 [64] Cao, Y., Zhao, L., Gutmann, T., Xu, Y., Dong, L., Buntkowsky, G.*, Gao, F.*, Getting Insights Into the Influence of Crystal Plane Effect of Shaped Ceria on Their Catalytic Performances, J. Phys. Chem. C 122, (2018), 20402-20409. DOI: 10.1021/acs.jpcc.8b06138 [63] Kumari, B., Brodrecht, M., Breitzke, H., Werner, M., Grünberg, B., Limbach, H.-H., Forg, S., Sanjon, E., Drossel, B., Gutmann, T.*, Buntkowsky, G.*, Mixtures of Alcohols and Water Confined in Mesoporous Silica- A Combined Solid-State NMR and Molecular Dynamic Simulation Study, J. Phys. Chem. C 122, (2018), 19540-19550. DOI: 10.1021/acs.jpcc.8b04745 [62] Rothermel, N., Bouzouita, D., Röther, T., Rosal del, I., Tricard, S., Poteau, R., Gutmann, T.*, Chaudret, B.*, Limbach, H.-H.*, Buntkowsky, G.*, Surprising Differences of Alkane C-H Activation catalyzed by Ruthenium Nanoparticles: Complex Surface-Substrate Recognition?, Chem. Cat. Chem. 10, (2018), 4243 – 4247. DOI: 10.1002/cctc.201801022R1 [61] Bothe, S., Nowag, J., Klimavičius, V., Hoffmann, M., Troitskaya, T., Amosov, E., Tormyshev, V., Kirilyuk, I., Taratayko, A., Kuzhelev, A., Parkhomenko, D., Bagryanskaya, E.*, Gutmann, T.*, Buntkowsky, G.*, Novel Biradicals for Direct Excitation Highfield Dynamic Nuclear Polarization, J. Phys. Chem. C 122, (2018), 11422-11432. DOI: 10.1021/acs.jpcc.8b02570 [60] Hoffmann, M.*, Bothe, S., Gutmann, T., Buntkowsky, G., Combining Freezing Point Depression and Self-Diffusion Data for Characterizing Aggregation, J. Phys. Chem. B 122, (2018), 4913-4921. DOI: 10.1021/acs.jpcb.8b03456 [59] Azim, M. M.*, Pensado, A., Kirchner, B., Gutmann, T., Groszewicz, P.B., Buntkowsky, G., Stark, A.∗, Ionothermal synthesis of crystalline microporous aluminophosphates: Systematic study on the conditions affecting the framework type, Micropor. Mesopor. Mat. 266, (2018), 204-213. DOI: 10.1016/j.micromeso.2018.02.053 [58] Kumari, B., John, D., Hoffmann, P., Spende, A., Toimil-Molares, M. E., Trautmann, C., Hess, C., Ruff, P., Schulze, M., Stark, R., Buntkowsky, G.*, Andrieu-Brunsen, A., Gutmann, T.*, Surface enhanced DNP assisted solid-state NMR of functionalized SiO2 coated Polycarbonate Membranes, Z. Phys. Chem., (2018), DOI: 10.1515/zpch-2017-1032 [57] Limbach, H.-H.*, Pery, T., Rothermel, N., Chaudret, B., Gutmann, T., Buntkowsky, G., Gas phase 1H NMR studies and kinetic modeling of dihydrogen isotope equilibration catalyzed by Ru-nanoparticles under normal conditions: dissociative vs. associative exchange, Phys. Chem. Chem. Phys. 20, (2018), 10697-10712. DOI: 10.1039/c7cp07770j [56] Brodrecht, M., Kumari, B., Breitzke, H., Gutmann, T., Buntkowsky, G.*, Chemically Modified Silica Materials as Model Systems for the Characterization of Water-Surface Interactions, Z. Phys. Chem., (2018), DOI: 10.1515/zpch-2017-1059 [55] Bothe, S., Hoffmann, M.*, Gutmann, T.*, Buntkowsky, G.*, Comparative Study of the Magnetic Field Depend Signal Enhancement in Solid-State Dynamic Nuclear Polarization Experiments, J. Phys. Chem. C 121, (2017), 27089−27097. DOI: 10.1021/acs.jpcc.7b07967 [54] Vowinkel, S., Paul, S., Gutmann, T., Gallei, M.*, Free-Standing and Self-Crosslinkable Hybrid Films by Core-Shell Particle Design and Processing, Nanomaterials 7, (2017), 390. DOI: 10.3390/nano7110390 [53] Hoffmann, M.*, Bothe, S., Gutmann, T.*, Buntkowsky, G.*, Unusual Local Molecular Motions in the Solid State Detected by Dynamic Nuclear Polarization Enhanced NMR Spectroscopy, J. Phys. Chem. C 121, (2017), 22948-22957. DOI: 10.1021/acs.jpcc.7b07965 [52] Thankamony, A. S. L., Knoche, S., Bothe, S., Drochner, A., Jagtap, A. P., Sigurdsson, S., Vogel, H., Etzold, B. J. M., Gutmann, T.*, Buntkowsky, G.*, Characterization of V-Mo-W Mixed Oxide Catalyst Surface Species by 51V Solid-State Dynamic Nuclear Polarization NMR, J. Phys. Chem. C 121, (2017), 20857-20864. DOI: 10.1021/acs.jpcc.7b06761 [51] Wang, Y., Groszewicz, P., Rosenfeldt, S., Schmidt, H., Volkert, C. A., Vana, P., Gutmann, T., Buntkowsky, G., Zhang, K.*, Thermo-reversible self-assembly of perfluorinated core-coronas cellulose-nanoparticles in dry state, Adv. Mater., (2017), 1702473. DOI: 10.1002/adma.201702473 [50] Liu, J., Groszewicz, P., Wen, Q., Thankamony, A. S. L., Zhang, B., Kunz, U., Sauer, G., Xu, Y., Gutmann, T.*, Buntkowsky, G.*, Revealing Structure Reactivity Relationships in Heterogenized Dirhodium Catalysts by Solid State NMR Techniques, J. Phys. Chem. C 121, (2017), 17409-17416. DOI: 10.1021/acs.jpcc.7b06807. [49] Ahrem, L., Scholz, G., Gutmann, T.*, Calvo, B., Buntkowsky, G., Kemnitz, E.*, Direct Observation of Coordinatively Unsaturated Sites on the Surface of a Fluoride-Doped Alumina Catalyst, J. Phys. Chem. C 121, (2017), 12206−12213. DOI: 10.1021/acs.jpcc.7b02535 [48] Gutmann, T.*, Buntkowsky, G.*, Solid-state NMR Studies of Supported Transition Metal Catalysts and Nanoparticles, in Modern Magnetic Resonance, Springer International Publishing AG, Cham, G. A. Webb (ed.), (2017), 1-21. DOI 10.1007/978-3-319-28275-6_39-1 [47] Gutmann, T.*, Kumari, B., Zhao, L., Breitzke, H.; Schöttner, S., Rüttiger, C., Gallei, M.*, DNP Signal Amplification as Sensitive Probe for Specific Functionalization of Complex Paper Substrates, J. Phys. Chem. C 121, (2017), 3896-3903. DOI: 10.1021/acs.jpcc.6b11751 [46] Hoffmann, M.*, Bothe, S., Gutmann, T.*, Hartmann, F., Reggelin, M., Buntkowsky, G.*, Directly vs. Indirectly Enhanced 13C in Dynamic Nuclear Polarization Magic Angle Spinning NMR Experiments of Nonionic Surfactant Systems, J. Phys. Chem. C 121, (2017), 2418-2424. DOI: 10.1021/acs.jpcc.6b13087 [45] Dubois, C., Herzog, N., Rüttiger, C., Geissler, A., Grange, E., Kunz, U., Kleebe, H.-J., Biesalski, M., Meckel, T., Gutmann, T., Gallei, M., Andrieu-Brunsen, A.*, Fluid Flow Programming in Paper-Derived Silica-Polymer Hybrids, Langmuir 33, (2017), 332–339. DOI: 10.1021/acs.langmuir.6b03839 [44] Gutmann, T., Alkhagani, S., Rothermel, N., Limbach, H.-H., Breitzke, H., Buntkowsky, G.*, 31P-Solid-State NMR Characterization and Catalytic Hydrogenation Tests of Novel heterogenized Iridium-Catalysts, Z. Phys. Chem. 231, (2017), 653–669. DOI: 10.1515/zpch-2016-0837 [43] Liu, J., Fasel, C., Braga-Groszewicza, P., Rothermel, N., Thankamony, A. S., Sauer, G., Xu, Y.*, Gutmann, T.*, Buntkowsky, G.*, Heterogeneous Self-Supported Dirhodium (II) Catalysts with High Catalytic Efficiency in Cyclopropanation – A structural study, Catal. Sci. Technol. 6, (2016), 7830–7840. DOI: 10.1039/C6CY00915H [42] Chadwick, F., Kraemer, T., Gutmann, T., Rees, N., Thompson, A., Edwards, A., Buntkowsky, G., Macgregor, S.*, Weller, A.*, Selective C-H Activation at a Molecular Rhodium Sigma-Alkane Complex by Solid/Gas Single-Crystal to Single-Crystal H/D Exchange, J. Amer. Chem. Soc. 38, (2016), 13369-13378. DOI:10.1021/jacs.6b07968 [41] Srour, M. Hadjiali, S., Sauer, G., i Brunnengräber, K., Breitzke, H., Xu, Y., Weidler, H., Limbach, H.-H., Gutmann, T.*, Buntkowsky, G.*, Synthesis and solid-state NMR characterization of a novel, robust, pyridyl-based immobilized Wilkinson’s type catalyst with high catalytic performance, Chem. Cat. Chem. 8, (2016), 3409 –3416. DOI: 10.1002/cctc.201600882R1 [40] Zhao, L., Smolarkiewicz, I., Limbach, H.-H., Breitzke, H., Pogorzelec-Glaser, K., Pankiewicz, R., Tritt-Goc, J.*, Gutmann, T.*, Buntkowsky, G.*, Imidazole Doped Cellulose as Membrane for Fuel Cells – Structural and Dynamic Insights from Solid-State NMR, J. Phys. Chem. C 120, (2016), 19574-19585. DOI: 10.1021/acs.jpcc.6b07049 [39] Scheid, D., Stock, D., Winter, T., Gutmann, T.*, Dietz, C., Gallei, M.*, The Pivotal Step of Nanoparticle Functionalization for the Preparation of Functional and Magnetic Hybrid Opal Films, J. Mater. Chem. C 4, (2016), 2187-2196. DOI:10.1039/c5tc04388c [38] Harrach, M., Drossel, B.*, Winschel, W., Gutmann, T., Buntkowsky, G.*, Mixtures of Isobutyric Acid and Water Confined in Cylindrical (Silica) Nanopores Revisited – A Combined Solid-State NMR and Molecular Dynamics Simulation Study, J. Phys. Chem. C 119, (2015), 28961–28969. DOI: 10.1021/acs.jpcc.5b09537 [37] Werner, M., Heil, A., Rothermel, N., Breitzke, H., Braga Groszewicz, P., Thankamony, A. S., Gutmann, T.*, Buntkowsky G.* Synthesis and Solid State NMR Characterization of Novel Peptide/Silica Hybrid Materials, Solid State NMR 72, (2015), 73-78. DOI: 10.1016/ j.ssnmr.2015.09.008 [36] Ratajczyk, T.*, Gutmann, T., Bernatowicz, P., Buntkowsky, G., Frydel, J., Fedorczyk, B. NMR Signal Enhancement by Effective SABRE Labelling of Oligopeptides. Chem. Eur. J. 21, (2015), 12616-12619. DOI: 10.1002/chem.201501552 [35] Buntkowsky, G.* Gutmann, T. A Mouse-Trap for Carbenium-Ions: NMR Detectives at Work. Angew. Chem.- Int. Ed. 54, (2015), 9450-9451. Eine Mausefalle für Carbenium-Ionen: NMR-Detektive bei der Arbeit. Angew. Chem. 127, (2015), 9582–9584. DOI: 10.1002/anie.201504899 [34] Cano, I., Huertos, M., Chapman, A., Buntkowsky, G., Gutmann, T., Groszewicz, P., van Leeuwen, P. W. N. M.* Air-Stable Gold Nanoparticles Ligated by Secondary Phosphine Oxides as Catalyst for the Chemoselective Hydrogenation of Substituted Aldehydes: a Remarkable Ligand Effect, J. Am. Chem. Soc. 137, (2015), 7718–7727. DOI: 10.1021/jacs.5b02802 [33] Liu, J., Plog, A., Groszewicz, P., Zhao, L., Xu, Y., Breitzke, H., Stark, A., Hoffmann, R., Gutmann, T.,* Zhang, K.,* Buntkowsky, G.* Design of a novel heterogeneous catalyst based on cellulose nanocrystals for cyclopropanation: Synthesis and solid-state NMR characterization. Chem. Eur. J. 21, (2015), 12414 -12420. DOI: 10.1002/chem.201501151 [32] Gutmann, T.*, Liu, J., Rothermel, N., Xu, Y., Jaumann, E., Werner, M., Breitzke, H., Sigurdsson, S. Th., Buntkowsky, G.* Natural abundance 15N NMR by Dynamic Nuclear Polarization: Fast Analysis of Binding Sites of a novel Amine-Carboxyl-linked Immobilized Dirhodium Catalyst. Chem. Eur. J. 21, (2015), 3798 – 3805. DOI: 10.1002/chem.201405043 [31] Zhao, L., Li, W., Plog, A., Xu, Y., Buntkowsky, G., Gutmann, T.*, Zhang, K.* Multi-responsive cellulose nanocrystal-rhodamine conjugates – An advanced structure study by solid-state dynamic nuclear polarization (DNP) NMR. Phys. Chem. Chem. Phys. 16, (2014), 26322 – 26329. DOI: 10.1039/c4cp04096a [30] Sauer, G., Nasu, D., Tietze, D., Gutmann, T., Englert, S., Avrutina, O., Kolmar, H.*, Buntkowsky, G.* Effective PHIP labeling of bioactive peptides boosts the intensity of the NMR signal. Angew. Chem.- Int. Ed. 53, (2014), 12941-12945. Effektive Markierung von bioaktiven Peptiden mit PHIP-Markern zur Steigerung der Empfindlichkeit von NMR-Signalen. Angew. Chem. 126, (2014), 13155 –13159. DOI: 10.1002/anie.201404668R1 and 10.1002/ange.201404668R1 [29] Buntkowsky, G., Gutmann, T., Petrova, M.V., Ivanov, K.L., Bommerich, U., Plaumann, M., Bernarding, J. Dipolar Induced Para-Hydrogen-Induced Polarization Solid State NMR 63-64, (2014), 20-29. DOI: 10.1016/j.ssnmr.2014.07.002 [28] Lego,D.*, Plaumann M., Trantzschel, T., Bargon J., Scheich, H., Buntkowsky, G., Gutmann, T., Sauer, G., Bernarding, J., Bommerich, U. Parahydrogen-induced polarization of carboxylic acids: a pilot study of valproic acid and related structures. NMR in Biomedicine 27 (2014), 810-816. DOI: 10.1002/nbm.3123 [27] Bonnefille, E., Novio, F., Gutmann, T., Poteau, R., Lecante, P., Jumas, J. C., Philippot, K.*, Chaudret, B.* Tin-decorated ruthenium nanoparticles: a way to tune selectivity in hydrogenation reaction. Nanoscale 6 (2014), 9806-9816. DOI:10.1039/C4NR00791C [26] Xu, Y., Watermann, T., Limbach, H.-H., Gutmann, T., Sebastiani, D., Buntkowsky, G.* Water and small organic molecules as probes for geometric confinement in well-ordered mesoporous carbon material. Phys. Chem. Chem. Phys. 16, (2014), 9327-9336. DOI:10.1039/C4CP00808A [25] Werner, M., Rothermel, N., Breitzke, H., Gutmann, T.*, Buntkowsky, G.* Recent Advances in Solid-State NMR of Small Molecules in Confinement. Isr. J. Chem. 54 (2014), 60-73. DOI: 10.1002/ijch.201300095 [24] Pieters, G., Taglang, C., Bonnefille, E., Gutmann, T., Puente, C., Berthet, J.-C., Dugave, C., Chaudret, B.*, Rousseau, B.* Regioselective and Stereospecific Deuteration of Bioactive Aza Compounds by the Use of Ruthenium Nanoparticles. Angew. Chem.- Int. Ed. 53, (2014), 230-234. DOI: 10.1002/anie.201307930 [23] Abdulhussain, S., Breitzke, H., Ratajczyk, T., Grünberg, A., Srour, M., Arnaut, D., Weidler H., Kunz, U., Kleebe, H. J., Bommerich, U., Bernarding, J., Gutmann, T.*, Buntkowsky, G.* Synthesis, Solid State NMR-Characterization and Application of a novel Wilkinson’s type immobilized Catalyst for hydrogenation reactions. Chem. Eur. J. 20, (2014), 1159-1166. DOI: 10.1002/chem.201303020 [22] Gutmann, T., Bonnefille, E., Breitzke, H., Debouttière, P.-J., Philippot, K., Poteau, R., Buntkowsky, G.*, Chaudret, B.* Investigation of the surface chemistry of phosphine-stabilized ruthenium nanoparticles – An advanced solid-state NMR study. Phys. Chem. Chem. Phys. 15, (2013), 17383-17394. DOI: 10.1039/c3cp52927d [21] Körner, M., Sauer, G., Heil, A., Nasu, D., Tietze, D., Voigt, S., Weidler, H., Gutmann, T., Avrutina, O., Kolmar, H., Ratajczyk, T.*, Buntkowsky, G.* PHIP-Label: Parahydrogen-Induced Polarization in Propargylglycine-Containing Synthetic Oligopeptides. Chem. Commun. 49, (2013), 7839-7841. DOI: 10.1039/C3CC43978J [20] Gutmann, T., Gruenberg, A., Rothermel, N., Werner, M., Srour, M., Abdulhussain, S., Xu, Y., Breitzke, H., Buntkowsky G.* Solid-State NMR Concepts for the Investigation of supported Transition Metal Catalysts and Nano-particles. Solid State NMR 55-56, (2013), 1-11. DOI: 10.1016/j.ssnmr.2013.06.004 [19] Grünberg, A., Gutmann, T., Rothermel, N., Xu, Y., Breitzke, H.*, Buntkowsky G.* Immobilization and Characterization of RuCl2(PPh3)3 on mesoporous Silica SBA-3. Z. Phys. Chem. 227, (2013), 901-915. DOI: 10.1524/zpch.2013.0398 [18] Gutmann, T., del Rosal, I., Chaudret, B., Poteau, R., Limbach, H.-H., Buntkowsky, G.* From molecular complexes to complex metallic nanostructures– 2H solid-state NMR studies of ruthenium containing hydrogenation catalysts. Chem. Phys. Chem. 14, (2013), 3026-3033. DOI: 10.1002/cphc.201300200 [17] Rafter, E., Gutmann, T., Löw, F., Buntkowsky, G., Philippot, K., Chaudret, B., van Leeuwen, P. W. N. M.* Secondary Phosphine Oxides as Pre-Ligands for Nanoparticle Stabilization. Catal. Sci. Technol. 3, (2013), 595-599. DOI: 10.1039/C2CY20683H [16] Trantzschel, T.*, Bernarding, J., Plaumann, M., Lego, D., Gutmann, T., Ratajczyk, T., Dillenberger, S., Buntkowsky, G., Bargon, J., Bommerich, U. Parahydrogen induced polarization in face of keto-enol tautomerism: proof of concept with hyperpolarized ethanol. Phys. Chem. Chem. Phys. 14, (2012), 5601-5604. DOI: 10.1039/C2CP40272F [15] Ratajczyk, T, Gutmann, T., Dillenberger, S., Abdulhussaein, S., Frydel, J., Breitzke, H., Bommerich, U., Trantzschel, T., Bernarding, J., Magusin, P., Buntkowsky, G.* Time Domain Para Hydrogen Induced Polarization. Solid State NMR 43–44, (2012), 14–21. DOI: 10.1016/j.ssnmr.2012.02.002 [14] del Rosal, I., Gutmann, T., Walaszek, B., Gerber, I. C., Chaudret, B., Limbach, H.-H., Buntkowsky, G., Poteau, R.* 2H NMR calculations on polynuclear transition metal complexes: on the influence of local symmetry. Phys. Chem. Chem. Phys. 13, (2011), 20199–20207. DOI: 10.1039/C1CP22081K [13] Gutmann, T., Ratajczyk, T., Dillenberger, S., Xu, Y., Grünberg, A., Breitzke, H., Bommerich, U., Trantzschel, T., Bernarding, J., Buntkowsky, G.* New investigations of technical rhodium and iridium catalysts in homogeneous phase employing Para-Hydrogen Induced Polarization. Solid State NMR 40, (2011), 88-90. DOI: 10.1016/j.ssnmr.2011.08.002 [12] Frydel, J. A., Krzystyniak, M., Pienkowski, D., Pietrzak, M., de Sousa Amadeu, N., Ratajczyk, T., Idzik, K., Gutmann, T., Tietze, D., Voigt, S., Fenn, A., Limbach, H.-H., Buntkowsky, G.* Efficient Design of Multituned Transmission Line NMR Probes: The Electrical Engineering Approach. Solid State NMR 39, (2011), 72-80. DOI: 10.1016/j.ssnmr.2011.01.001 [11] Tietze, D., Voigt, S., Mollenhauer, D., Tischler, M., Imhof, D. Gutmann, T., González, L., Ohlenschläger, O., Breitzke, H., Görlach, M. Buntkowsky, G.* Revealing the position of the substrate in NiSOD: a model study. Angew. Chem. – Int. Ed. 50, (2011), 2946-2950. Bestimmung der Substratposition in der Nickel-Superoxiddismutase: eine Modellstudie Angew. Chem. 123, (2011), 3002-3006. DOI: 10.1002/anie.201005027 and 10.1002/ange.201005027 [10] Gutmann, T., Ratajczyk; T., Xu, Y., Breitzke, H., Gruenberg, A., Dillenberger, S., Bommerich, U., Trantzschel, T., Bernarding, J., Buntkowsky, G.* Understanding the leaching Properties of heterogenized Catalysts: a combined Solid State and PHIP NMR Study. Solid State NMR 38, (2010), 90-96. DOI: 10.1016/j.ssnmr.2011.03.001 [9] Gutmann, T., Walaszek, B., Xu, Y., Wächtler, M., del Rosal, I., Grünberg, A., Poteau, R., Axet, R., Lavigne, G., Chaudret, B., Limbach, H.-H, Buntkowsky, G.* Hydrido-ruthenium cluster complexes as models for reactive surface hydrogen species of ruthenium nanoparticles – Solid-state 2H NMR and quantum chemical calculations. J. Am. Chem. Soc. 132, (2010), 11759-11767. DOI: 10.1021/ja104229a [8] Gutmann,T., Sellin, M., Breitzke, H., Stark, A., Buntkowsky, G.* Para-Hydrogen Induced Polarization in Homogeneous Phase – An Example of how Ionic Liquids Affect Homogenization and thus Activation of Catalysts. Phys. Chem. Chem. Phys. 11, (2009), 9170-9175. DOI: 10.1039/b908198d [7] del Rosal, I., Gutmann, T., Maron, L., Jolibois, F., Chaudret, B., Walaszek, B., Limbach, H.-H, Poteau, R.*, Buntkowsky, G.* DFT 2H quadrupolar coupling constants of ruthenium complexes: A good probe of the coordination of hydrides in conjunction with experiments. Phys. Chem. Chem. Phys. 11, (2009), 5657-5663. DOI: 10.1039/B822150B [6] Fenn, A., Wächtler, M., Gutmann, T., Breitzke, H., Buchholz, A., Lippold, I., Plass, W., Buntkowsky, G.* Correlations between 51V solid-state NMR parameters and chemical structure of vanadium (V) complexes as models for related metalloproteins and catalysts. Solid State NMR 36, (2009), 192-201. DOI: 10.1016/j.ssnmr.2009.11.003 [5] Wächtler, M., Schweitzer, A., Gutmann, T., Breitzke, H., Buntkowsky, G.* Effcient analysis of 51V solid-state MAS NMR spectra using genetic algorithms. Solid State NMR 35, (2009), 37-48. DOI: 10.1016/j.ssnmr.2008.11.003 [4] Walaszek, B., Adamczyk, A., Pery,T., Xu, Y., Gutmann, T., Amadeu de Sousa, N., Ulrich, S., Breitzke H., Vieth, H. M., Sabo-Etienne, S., Chaudret, B., Limbach, H.-H, Buntkowsky, G.* 2H solid-state NMR of ruthenium complexes. J. Am. Chem. Soc.130, (2008), 17502-17508. DOI: 10.1021/ja806344y [3] Gutmann, T., Schweitzer, A., Wächtler, M., Breitzke, H., Buchholz, A., Plass, W., Buntkowsky, G.* DFT calculations of 51V solid-state NMR parameters of vanadium(V) model complexes. Z. Phys. Chem. 222, (2008), 1389-1406. DOI: 10.1524/zpch.2008.5401 [2] Schweitzer, A., Gutmann, T., Wächtler, M., Breitzke, H., Buchholz, A., Plass, W., Buntkowsky, G.* 51V solid-state NMR investigations and DFT studies of model compounds for vanadium haloperoxidases. Solid State NMR 34 (2008), 52-67. DOI: 10.1016/j.ssnmr.2008.02.003 [1] Buntkowsky, G.*, Limbach, H.H., Walaszek, B., Adamczyk, A., Xu, Y., Breitzke, H., Schweitzer, A., Gutmann, T., Wächtler, M., Frydel, J., Emmler, T., Amadeu, N., Tietze, D., Chaudret, B. Mechanism of dipolar ortho-/para-H2O conversion in ice. Z. Phys. Chem. 222, (2008), 1049-1063. DOI: 10.1524.zpch.2008.5359 |