Publikationen

M. Alcaraz Janßen, C. M. Thiele*

Poly‐γ‐S‐perillyl‐L‐glutamate and Poly‐γ‐S‐perillyl‐D‐glutamate: diastereomeric alignment media used for the investigation of the alignment process

Chem. Eur. J. 2020, 26, 7831-7839

DOI: 10.1002/chem.201905447

D. Sinnaeve,* J. Ilgen, M. E. Di Pietro, J. J. Primozic, V. Schmidts, C. M. Thiele, B. Luy

Probing long-range anisotropic interactions – A general and sign-sensitive strategy to measure ¹H-¹H residual dipolar couplings as a key advance for organic structure determination

Angew. Chem. 2020, 132, 5354-5358, Angew. Chem. Int. Ed. 2020, 59, 5316-5320

DOI: 10.1002/ange.201915278, 10.1002/anie.201915278

[Raw Data: DOI 10.6084/m9.figshare.11297651]

D. Niedek, F. R. Erb, C. Topp, A. Seitz, R. C. Wende, A. K. Eckhardt, J. Kind, D. Herold, C. M. Thiele,* P. R. Schreiner*

In situ Switching of Site-Selectivity with Light in the Acetylation of Sugars with Azo-Peptide Catalysts

J. Org. Chem. 2020, 85, 1835-1846

DOI: 10.1021/acs.joc.9b01913

J. von Irmer, F. Frieß, D. Herold, J. Kind, C. M. Thiele,* M. Gallei*

Photochromic Dithienylethenes Characterized by in situ Irradiation NMR-Spectroscopy and Electrochemically-Induced Responsiveness on Gold Substrates

J. Mater. Chem. C 2019, 7, 14088-14097

DOI: 10.1039/C9TC04495G

J. Kind,* C. M. Thiele

MRI and localised NMR spectroscopy of sessile droplets on hydrophilic, hydrophobic and superhydrophobic surfaces – Examination of the chemical composition during evaporation

J. Magn. Reson. 2019, 307, 106579

DOI: 10.1016/j.jmr.2019.106579

[Raw Data: DOI 10.23728/b2share.5f4f0b7ae6d84ab8bdab95131d6ed0a3]

M. Hirschmann, M. Schwab, C. M. Thiele*

Molecular Weights: The Key for Lyotropic Liquid Crystalline Phases of Poly-β-benzyl-L-aspartate

Macromolecules 2019, 52, 6025-6034

DOI: 10.1021/acs.macromol.9b00970

Y. Ji,* D. DiRocco, J. Kind, C. M. Thiele, R. M. Gschwind, M. Reibarkh*

LED Illuminated NMR spectroscopy: Practical Tool for Mechanistic Studies of Photochemical Reactions

ChemPhotoChem 2019, 3, 984-992

DOI: 10.1002/cptc.201900109

A. Matt, B. Kuttich,* I. Grillo, S. Weißheit, C. M. Thiele, B. Stühn

Temperature induced conformational changes in the elastin-like peptide GVG(VPGVG)₃

Soft Matter 2019, 15, 4192-4199

DOI: 10.1039/C9SM00583H

K. Knoll, M. Leyendecker, C. M. Thiele*

L‐Valine derivatised 1,3,5‐Benzene‐tricarboxamides as Building Blocks for a new Supramolecular Organogel‐like Alignment Medium

Eur. J. Org. Chem. 2019, 2019, 720-727

DOI: 10.1002/ejoc.201801306

S. Jeziorowski, C. M. Thiele*

Poly‐γ‐p‐biphenylmethyl‐glutamate as Enantiodifferentiating Alignment Medium for NMR‐Spectroscopy with Temperature Tunable Properties

Chem. Eur. J. 2018, 24, 15631-15637

DOI: 10.1002/chem.201802921

M. Schwab, V. Schmidts, C. M. Thiele*

Thermoresponsive Alignment Media in NMR spectroscopy: Helix Reversal of a Copolyaspartate at Ambient Temperatures

Chem. Eur. J. 2018, 24, 14373-14377

DOI: 10.1002/chem.201803540

J. Ilgen, L. Kaltschnee, C. M. Thiele*

perfectBASH: Band-selective homonuclear decoupling in peptides and peptidomimetics

Magn. Reson. Chem. 2018, 56, 918-933

DOI: 10.1002/mrc.4757

[Raw Data: DOI 10.23728/b2share.688901f6e4fe4b92bd0238715c3186bb]

A.-K. Schönbein, J. Kind, C. M. Thiele,* J. J. Michels*

Full Quantification of the Light-Mediated Gilch Polymerization

Macromolecules 2018, 51, 4678-4687

DOI: 10.1021/acs.macromol.8b00607

L. Čechová, J. Kind, M. Dračínský, J. Filo, Z. Janeba, C. M. Thiele, M. Cigáň,* E. Procházková*

Photoswitching behavior of 5-phenylazopyrimidines: in situ irradiation NMR and optical spectroscopy combined with theoretical methods

J. Org. Chem. 2018, 83, 5986-5998

DOI: 10.1021/acs.joc.8b00569

E. Procházková,* L. Čechová, J. Kind, Z. Janeba, C. M. Thiele, M. Dračínský*

Photoswitchable intramolecular hydrogen bonds in 5-phenylazopyrimidines revealed by in-situ irradiation NMR spectroscopy

Chem. Eur. J. 2018, 24, 492-498

DOI: 10.1002/chem.201705146

J. Ilgen, L. Kaltschnee, C. M. Thiele*

A pure shift experiment with increased sensitivity and superior performance for strongly coupled systems

J. Magn. Reson. 2018, 286, 18-29

DOI: 10.1016/j.jmr.2017.11.001

[JMR Most-read Publication Award in 2018] [Raw Data: DOI 10.23728/b2share.76f2f9e3f53d4fce90e2ac768102c34e]

S. Ortgies, R. Rieger, K. Rode, K. Koszinowski, J. Kind, C. M. Thiele, J. Rehbein, A. Breder*

Mechanistic and Synthetic Investigations on the Dual Selenium-π-Acid/Photoredox Catalysis in the Context of the Aerobic Dehydrogenative Lactonization of Alkenoic Acids

ACS Catal. 2017, 7, 7578-7586

DOI: 10.1021/acscatal.7b02729

M. Schwab, D. Herold, C. M. Thiele*

Polyaspartates as Thermoresponsive Enantiodifferentiating Helically Chiral Alignment Media for Anisotropic NMR-Spectroscopy

Chem. Eur. J. 2017, 23, 14576-14584

DOI: 10.1002/chem.201702884

M. Leyendecker, N.-C. Meyer, C. M. Thiele*

Development of new supramolecular lyotropic liquid crystals and their application as alignment media for organic compounds

Angew. Chem. 2017, 129, 11629-11632, Angew. Chem. Int. Ed. 2017, 56, 11471-11474

DOI: 10.1002/ange.201705642, 10.1002/anie.201705642

S. Hansmann, V. Schmidts, C. M. Thiele*

Synthesis of Poly-γ-S-2-methylbutyl-L-glutamate and Poly-γ-S 2-methylbutyl-D-glutamate and their Use as Enantiodiscriminating Alignment Media in NMR Spectroscopy

Chem. Eur. J. 2017, 23, 9114-9121

DOI: 10.1002/chem.201700699

M. Fredersdorf, M. Kurz, A. Bauer, M.-O. Ebert, C. Rigling, L. Lannes, C. M. Thiele*

Conformational analysis of an antibacterial cyclodepsipeptide active against M. tuberculosis by a combined ROE and RDC analysis

Chem. Eur. J. 2017, 24, 5729-5735

DOI: 10.1002/chem.201605143

[Back Cover]

Yu. E. Moskalenko, V. Bagutski, C. M. Thiele*

Chemically synthesized and cross-linked PDMS as versatile alignment medium for organic compounds

Chem. Commun. 2017, 53, 95-98

DOI: 10.1039/C6CC08762K

[Inside Front Cover]

E. Procházková, A. Kolmer, J. Ilgen, M. Schwab, L. Kaltschnee, M. Fredersdorf, V. Schmidts, R. C. Wende, P. R. Schreiner,* C. M. Thiele*

Uncovering Key Structural Features of an Enantioselective Peptide-Catalyzed Acylation Utilizing Advanced NMR Techniques

Angew. Chem. 2016, 128, 15986–15991, Angew. Chem. Int. Ed. 2016, 55, 15754–15759

DOI: 10.1002/ange.201608559, 10.1002/anie.201608559

S. Hörner, S. Knauer, C. Uth, M. Jöst, V. Schmidts, H. Frauendorf, C. M. Thiele, O. Avrutina, H. Kolmar*

Nanoscale Biodegradable Organic–Inorganic Hybrids for Efficient Cell Penetration and Drug Delivery

Angew. Chem. 2016, 128, 15063-15068, Angew. Chem. Int. Ed. 2016, 55, 14842-14846

DOI: 10.1002/ange.201606065, 10.1002/anie.201606065

J. Kind, L. Kaltschnee, M. Leyendecker, C. M. Thiele*

Distinction of trans-cis photoisomers with comparable optical properties in multiple-state photochromic systems – Examining a molecule with three azobenzenes via in situ irradiation NMR

Chem. Commun. 2016, 52, 12506-12509

DOI: 10.1039/C6CC06771A

I. Timári, L. Kaltschnee, M. H. Raics, F. Roth, N. G. A. Bell, R. W. Adams, M. Nilsson, D. Uhrín, G. A. Morris, C. M. Thiele, K. E. Kövér

Real-time broadband proton-homodecoupled CLIP/CLAP-HSQC for automated measurement of heteronuclear one-bond coupling constants

RSC Adv. 2016, 6, 87848-87855

DOI: 10.1039/C6RA14329F

L. Kaltschnee, K. Knoll, V. Schmidts, R. W. Adams, M. Nilsson, G. A. Morris, C. M. Thiele*

Extraction of Distance Restraints from Pure Shift NOE experiments

J. Magn. Reson. 2016, 271, 99-109

DOI: 10.1016/j.jmr.2016.08.007

M. R. M. Koos, G. Kummerlöwe, L. Kaltschnee, C. M. Thiele,* B. Luy*

CLIP-COSY: A Clean Inphase Experiment for Rapid Acquisition of COSY-type Correlations

Angew. Chem. 2016, 128, 7785-7789, Angew. Chem. Int. Ed. 2016, 55, 7655-7659

DOI: 10.1002/ange.201510938, 10.1002/anie.201510938

F. Krohm, J. Kind, R. Savka, M. Alcaraz Janßen, D. Herold, H. Plenio, C. M. Thiele, A. Andrieu-Brunsen*

Photochromic spiropyran- and spirooxazine-homopolymers in mesoporous thin films by surface initiated ROMP

J. Mater. Chem. C 2016, 4, 4067-4076

DOI: 10.1039/C5TC04054J | Corrigendum

S. Hansmann, T. Larem (née Montag), C. M. Thiele*

Enantiodifferentiating properties of the alignment media PELG and PBLG -- A comparison

Eur. J. Org. Chem. 2016, 7, 1324–1329

DOI: 10.1002/ejoc.201501410

N. Kolmer-Anderl, A. Kolmer, C. M. Thiele,* M. Rehahn*

Exploration of the photodegradation of naphto[2,3-g]quinoxalines and pyrazino[2,3-b]phenazines

Chem. Eur. J. 2016, 22, 5277–5287

DOI: 10.1002/chem.201504453

C. Wolff, J. Kind, H. Schenderlein, H. Bartling, C. Feldmeier, M. Biesalski, R. M. Gschwind, C. M. Thiele*

Studies of a photochromic model system using NMR with ex-situ and in-situ irradiation devices

Magn. Reson. Chem. 2016, 54, 485-491

DOI: 10.1002/mrc.4403

A. Kolmer, L. J. Edwards, I. Kuprov, C. M. Thiele*

Conformational analysis of small organic molecules using NOE and RDC data: A discussion of strychnine and alpha-methylene-gamma-butyrolactone

J. Magn. Reson. 2015, 261, 101-109

DOI: 10.1016/j.jmr.2015.10.007

J. Kind, C. M. Thiele*

Still shimming or already measuring? – Quantitative reaction monitoring for small molecules on the sub minute timescale by NMR

J. Magn. Reson. 2015, 260, 109-115

DOI: 10.1016/j.jmr.2015.09.008

M. Fredersdorf, R. Göstl, A. Kolmer, V. Schmidts, P. Monecke, S. Hecht,* C. M. Thiele*

Exploring the Conformational Space of Bridge-Substituted Dithienylcyclopentenes

Chem. Eur. J. 2015, 21, 14545–14554

DOI: 10.1002/chem.201501842

L.-G. Xie, V. Bagutski, D. Audisio, L. Wolf, V. Schmidts, K. Hofmann, C. Wirtz, W. Thiel, C. M. Thiele,* N. Maulide*

Dynamic Behaviour of monohaptoallylpaladium species: internal coordination as a driving force in allylic alkylation chemistry

Chem. Sci. 2015, 6, 5734-5739

DOI: 10.1039/C5SC01867F

B. Horstmann, M. Korbus, T. Friedmann, C. Wolff, C. M. Thiele, F.-J. Meyer-Almes*

Synthesis of azobenzenealkylmaleimide probes to photocontrol the enzyme activity of a bacterial histone deacetylase-like amidohydrolase

Bioorg. Chem. 2014, 57, 155-161

DOI: 10.1016/j.bioorg.2014.10.004

L. Kaltschnee, A. Kolmer, I. Timári, V. Schmidts, R. W. Adams, M. Nilsson, K. E. Kövér, G. A. Morris, C. M. Thiele*

„Perfecting“ pure shift HSQC: full homodecoupling for accurate and precise determination of heteronuclear couplings

Chem. Commun. 2014, 50, 15702-15705

DOI: 10.1039/C4CC04217D

I. Timári, L. Kaltschnee, A. Kolmer, R. W. Adams, M. Nilsson, C. M. Thiele, G. A. Morris, K. E. Kövér*

Accurate determination of one-bond heteronuclear coupling constants with “pure shift” broadband proton-decoupled CLIP/CLAP-HSQC experiments

J. Magn. Reson. 2014, 239, 130-138

DOI: 10.1016/j.jmr.2013.10.023

V. Thiel, K.-J. Wannowius, C. Wolff, C. M. Thiele, H. Plenio*

Ring-Closing Metathesis Reactions: Interpretation of Conversion–Time Data

Chem. Eur. J. 2013, 19, 16403–16414

DOI: 10.1002/chem.201204150

A. Kolmer, L. Kaltschnee, V. Schmidts, L. H. Peeck, H. Plenio, C. M. Thiele*

The influence of electronic modifications on rotational barriers of bis-NHC-complexes as observed by dynamic NMR spectroscopy

Magn. Reson. Chem. 2013, 51, 695–700

DOI: 10.1002/mrc.4002

V. Schmidts, M. Fredersdorf, T. Lübken, A. Porzel, N. Arnold, L. Wessjohann,* C. M. Thiele*

RDC-Based Determination of the Relative Configuration of the Fungicidal Cyclopentenone 4,6-Diacetylhygrophorone A¹²

J. Nat. Prod. 2013, 76, 839-844

DOI: 10.1021/np300728b

T. Montag, C. M. Thiele*

Cross-Linked Helically Chiral Poly-(γ-benzyl-L-glutamate) as Enantiodiscriminating Alignment Medium

Chem. Eur. J. 2013, 19, 2271-2274

DOI: 10.1002/chem.201202554

P. Giraudeau,* T. Montag, B. Charrier, C. M. Thiele*

Fast access to residual dipolar couplings by single-scan 2D NMR in oriented media

Magn. Reson. Chem. 2012, 50, S53–S57

DOI: 10.1002/mrc.3856 | Corrigendum

N.-C. Meyer, A. Krupp, V. Schmidts, C. M. Thiele, M. Reggelin*

Polyacetylenes as Enantiodifferentiating Alignment Media

Angew. Chem. 2012, 124, 8459–8463, Angew. Chem. Int. Ed. 2012, 51, 8334–8338

DOI: 10.1002/ange.201201891, 10.1002/anie.201201891

R. Berger, J. Courtieu, R. R. Gil, C. Griesinger,* M. Köck, P. Lesot, B. Luy, D. Merlet, A. Navarro-Vázquez, M. Reggelin, U. M. Reinscheid, C. M. Thiele, M. Zweckstetter

Is Enantiomer Assignment Possible by NMR Spectroscopy Using Residual Dipolar Couplings from Chiral Nonracemic Alignment Media? – A Critical Assessment

Angew. Chem. 2012, 124, 8512–8515, Angew. Chem. Int. Ed. 2012, 51, 8388–8391

DOI: 10.1002/ange.201107626, 10.1002/anie.201107626

C. M. Thiele,* W. Bermel

Speeding up the measurement of one-bond scalar (1J) and residual dipolar couplings (1D) by using non-uniform sampling (NUS)

J. Magn. Reson. 2012, 216, 134-143

DOI: 10.1016/j.jmr.2012.01.008 | Corrigendum

G. Kummerlöwe, S. L. Grage, C. M. Thiele, I. Kuprov, A. S. Ulrich, B. Luy*

Variable Angle NMR Spectroscopy and Its Application to the Measurement of Residual Chemical Shift Anisotropy

J. Magn. Reson. 2011, 209, 19-30

DOI: 10.1016/j.jmr.2010.11.019

D. Zornik, R. M. Meudtner, T. El Malah, C. M. Thiele, S. Hecht*

Designing Structural Motifs for Clickamers: Exploiting the 1,2,3-Triazole Moiety to Generate Conformationally Restricted Architectures

Chem. Eur. J. 2011, 17, 1473-1484

DOI: 10.1002/chem.201002491

C. M. Thiele,* W. C. Pomerantz, N. L. Abott, S. H. Gellman

Lyotropic liquid crystalline phases from helical β-peptides as alignment media

Chem. Commun. 2011, 47, 502-504

DOI: 10.1039/C0CC02123G

U. M. Reinscheid,* M. Köck,* C. Cychon, V. Schmidts, C. M. Thiele,* C. Griesinger*

The Absolute Configuration of Dibromopalau'amine

Eur. J. Org. Chem. 2010, 6900-6903

DOI: 10.1002/ejoc.201001392

L. Arnold, A. Marx, C. M. Thiele, M. Reggelin*

Polyguanidines as Chiral Orienting Media for Organic Compounds

Chem. Eur. J. 2010, 16, 10342-10346

DOI: 10.1002/chem.201000940

A. Marx, B. Böttcher, C. M. Thiele*

Enhancing the Orienting Properties of Poly(γ-benzyl-L-glutamate) by means of Additives

Chem. Eur. J. 2010, 16, 1656-1663

DOI: 10.1002/chem.200902287

B. Böttcher, V. Schmidts, J. A. Raskatov, C. M. Thiele*

Determination of the Conformation of the Key Intermediate in an Enantioselective Palladium-Catalyzed Allylic Substitution from Residual Dipolar Couplings

Angew. Chem. 2010, 122, 210-214, Angew. Chem. Int. Ed. 2010, 49, 205-209

DOI: 10.1002/ange.200903649, 10.1002/anie.200903649

C. M. Thiele,* A. Maliniak, B. Stevensson

Use of Local Alignment Tensors for the Determination of Relative Configurations in Organic Compounds

J. Am. Chem. Soc. 2009, 131, 12878-12879

DOI: 10.1021/ja904536b

C. M. Thiele,* V. Schmidts, B. Böttcher, I. Louzao, R. Berger, A. Maliniak, B. Stevensson

On the Treatment of Conformational Flexibility when using Residual Dipolar Couplings for Structure Determination

Angew. Chem. 2009, 121, 6836-6840, Angew. Chem. Int. Ed. 2009, 48, 6708-6712

DOI: 10.1002/ange.200902398, 10.1002/anie.200902398

A. Marx, V. Schmidts, C. M. Thiele*

How different are diastereomorphous orientations of enantiomers in the liquid crystalline phases of PBLG and PBDG: a case study

Magn. Res. Chem. 2009, 47, 734-740

DOI: 10.1002/mrc.2454

C. M. Thiele,* K. Petzold, J. Schleucher*

EASY ROESY: Reliable Cross-Peak Integration in Adiabatic Symmetrized ROESY

Chem. Eur. J. 2009, 15, 585-588

DOI: 10.1002/chem.200802027

R. S. Stoll, M. V. Peters, A. Kühn, S. Heiles, R. Goddard, M. Bühl, C. M. Thiele,* S. Hecht*

Photoswitchable Catalysts: Correlating Structure and Conformational Dynamics with Reactivity by a Combined Experimental and Computational Approach

J. Am. Chem. Soc. 2009, 131, 357-367

DOI: 10.1021/ja807694s

A. Marx, C. M. Thiele*

Orientational properties of PBLG: Influence of molecular weight and solvent on order parameters of the solute

Chem. Eur. J. 2009, 15, 254-260

DOI: 10.1002/chem.200801147

C. M. Thiele*

Residual Dipolar Couplings (RDCs) in Organic Structure Determination

Eur. J. Org. Chem. 2008, 5673-5685

DOI: 10.1002/ejoc.200800686

S. Leuthäußer, V. Schmidts, C. M. Thiele,* H. Plenio*

π-Face Donor Properties of N-Heterocyclic Carbenes in Grubbs II Complexes

Chem. Eur. J. 2008, 14, 5465-5481

DOI: 10.1002/chem.200800139

C. M. Thiele*

Magnetic Resonance at or below the Earth's magnetic field

Angew. Chem. 2007, 119, 4904-4909; Angew. Chem. Int. Ed. 2007, 46, 4820-24

DOI: 10.1002/ange.200700730, 10.1002/anie.200700730

C. M. Thiele,* A. Marx, R. Berger, J. Fischer, M. Biel, A. Giannis

Determination of the relative configuration of a five-membered ring compound using RDCs

Angew. Chem. 2006, 118, 4566-4571, Angew. Chem. Int. Ed. 2006, 45, 4455-4460

DOI: 10.1002/ange.200503247, 10.1002/anie.200503247

C. M. Thiele*

Poly-γ-ethyl-Lglutamate as Alignment Medium for the Measurement of RDCs in Organic Substrates

J. Org. Chem.2004, 69, 7403-7413

DOI: 10.1021/jo049867w

C. M. Thiele,* S. Berger

Probing the Diastereotopicity of Methylene Protons in Strychnine Using Residual Dipolar Couplings

Org. Lett. 2003, 5, 705-708

DOI: 10.1021/ol0275163