Polymer Synthesis and Characterization

In polymer reaction engineering the statement "polymers are products by process" applies. This means that polymer properties do not only depend on the chemistry of the monomer building blocks, but are also determined to a significant extent by the process itself. Molecular weight, dispersity, branching densities or copolymer compositions are directly determined by the polymerization process. Consequently, the understanding of process-structure-property relationships offers the possibility to optimize polymerization processes and products in a sustainable way.

Solution Polymerization

Connecting of process conditions with product properties; Macromolecular Rapid Communications 12-2022; Photo-Credit to Wiley-VCH GmbH. [1]

Solution polymerizations are a widely used process in chemical industry for the production of relevant polymer materials, such as adhesives or coatings. Typical industrial examples are polyacrylates, and -methacrylates, polyacrylic acid, polyvinyl acetate and more. They take place under varying conditions, such as temperatures, solvents, initiators and more, so that a wide range of products is accessible. The advantage is that all substances involved are present in one phase during the entire reaction time.

[1]https://onlinelibrary.wiley.com/doi/10.1002/marc.202270032

Emulsion Polymerization

Schematic representation of an emulsion polymerization
Schematic representation of an emulsion polymerization

Polymer dispersions are polymer particles finely dispersed in a continuous phase – typically water. These products have a very wide range of applications and can be found, for example, as latex paints or adhesives, in paper coating or encapsulation of inorganic particles, and for biomedical or pharmaceutical purposes. They are often produced by emulsion polymerization in batch or semi-batch processes. For this purpose, water, emulsifier and monomer are initially charged, then emulsified and initiator solution and, if necessary, further monomer are added.